Reference tables for thermocouples of iridium-rhodium alloys versus iridium

Vapor Pressures of Platinum , Iridium , and Rhodium

Systematic measurements of the vapor pressure of iridium and rhodium over a wide temperatme range have not been published previously. A summary of previous estimates or observations of their normal boiling points and values of their heats of sublimation, f:..H ~ (298), is given in table l. The vapor pressure of platinum was calculated by Langmuir and .Mackay from measurements of the rate of sub...

Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides.

Picosecond time-resolved infrared spectroscopy was used to elucidate early photochemical processes in the diazido complexes M(Cp*)(N3)2(PPh3), M = Rh (), Ir (), using 266 nm and 400 nm excitation in THF, CH2Cl2, MeCN and toluene solutions. The time-resolved data have been interpreted with the aid of DFT calculations on vibrational spectra of the singlet ground states and triplet excited states ...

Chemical vapor deposition of iridium, platinum, rhodium and palladium

Rhodium and iridium complexes with a new scorpionate phosphane ligand.

A straightforward synthesis of a new hybrid scorpionate ligand [(allyl)2B(CH2PPh2)(Pz)](-) ([A2BPN](-)) is reported. Coordination to rhodium resulted in square-planar complexes [Rh(κ(2)-A2BPN)(L)(L')] [L = L' = (1)/2cod (1,5-cyclooctadiene), CN(t)Bu, CO (6); L = CO, L' = NH3, pyridine, PPh3, PMe3] for which spectroscopic data and the molecular structure of [Rh(κ(2)-A2BPN)(CO)PPh3] (11) indicate...

Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands

The neutral chloro complexes [(g-C5Me5)M(g-NC9H6O)Cl] as well as the cationic aqua complexes [(g-C5Me5)M(g-NC9H6O)(H2O)] (M = Rh, Ir) have been synthesized from the reaction of the dinuclear precursors [(g-C5Me5)MCl2]2 and 8-hydroxyquinoline. The single crystal X-ray structure analysis of [(g-C5Me5)Ir(g-NC9H6O)Cl] reveals for these complexes a piano-stool arrangement with the aromatic ligand, t...